Molecular geometry describes the three-dimensional structure of a molecule. Bond angles: The angle between adjacent bonds of an atom.Hybridization: Orbitals are combined in order to spread out electrons.Molecular Geometry: Describes the arrangement of atoms around the central atom with acknowledgment to only bonding electrons.Electron Geometry: Describes the arrangement of bonds and lone pairs around a central atom.If you enjoy this tutorial, feel free to check out our other tutorials on bonding listed below. You will learn about the more common molecular geometries: tetrahedral, linear, bent, trigonal pyramidal, and trigonal planar – along with their bond angles. With the aid of the developed method, numerous earlier studies can be better understood, and the performance of spin qubits can be further optimized in the future.In this tutorial, you will learn how to identify the molecular geometry and bond angles of a molecule. Similarly to the binding of two atoms to a molecule, the wave functions of two electrons must lie on one plane for successful entanglement. The spatial orientation of the electrons also plays a role in the entanglement of several spins. This gives us the opportunity to optimize control of the spins in a very targeted manner," says Zumbühl. "We are able to not only map the shape and orientation of the electron, but also control the wave function according to the configuration of the applied electric fields. The researchers, who work closely with colleagues in Japan, Slovakia and the US, thus gain a better understanding of the correlation between the geometry of electrons and the electron spin, which should be stable for as long as possible and quickly switchable for use as a qubit. "To put it simply, we can use this method to show what an electron looks like for the first time," explains Loss. Based on their theoretical model, it is possible to determine the electron's probability density and thus its wave function with a precision on the sub-nanometer scale. The scientists use spectroscopic measurements to determine the energy levels in the quantum dot and study the behavior of these levels in magnetic fields of varying strength and orientation. However, it moves within the space and, with different probabilities corresponding to a wave function, remains in specific locations within its confinement. The electron is held in the quantum dot by electric fields. Because the trapped electrons behave similarly to electrons bound to an atom, quantum dots are also known as "artificial atoms." Scientists in the teams headed by professors Dominik Zumbühl and Daniel Loss from the Department of Physics and the Swiss Nanoscience Institute at the University of Basel have now developed a method by which they can spatially determine the geometry of electrons in quantum dots.Ī quantum dot is a potential trap which allows confining free electrons in an area which is about 1000 times larger than a natural atom. The stability of a single spin and the entanglement of various spins depends, among other things, on the geometry of the electrons-which previously had been impossible to determine experimentally. Controlling and switching this spin or coupling it with other spins is a challenge on which numerous research groups worldwide are working. The spin of an electron is a promising candidate for use as the smallest information unit (qubit) of a quantum computer.
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Verify that all safety equipment is present.Verify that all safety and control stickers and labels are present and legible.Verify that the data plate is present, legible, and represents the configuration in use.The pre-use inspection can include the following, however refer to the user’s manual for the type of machine you are using: A forklift does not need to be inspected on any day that it is not used. Always refer to manufacturer provided manuals for appropriate inspections guidance. If at any time a forklift is found to be in-need of repair, defective, or in any way unsafe, the forklift shall be removed from service until it has been restored to safe operating condition. Inspection, Fueling, Charging, and Maintenance ProceduresĪ pre-use inspection identifies potential hazards that may be encountered from a damaged forklift and must be performed at least daily by the operator before operation. Comply with all regulations and UT’s Powered Industrial Truck/Forklift safety guidance.Ensure they have passed forklift training and evaluation before operating a powered industrial truck/forklift on campus.May audit a department or responsible unit and assign training as necessary.Provide forklift safety training upon request from the supervisor. Review and audit powered industrial truck/forklift safety training as necessary.Ensure that forklifts are repaired when malfunctioning and maintained, or taken out of service until such repairs can be made.
I'd like to announce Ren'Py 8.0.0, the first release of Ren'Py based on This release also includes a new Ukrainian translation of the Prevented upgrading from Ren'Py 7.4 when Steam support was installed. This release fixes multiple issues with Ren'Py 8.0.0, including one that Please see theĬhangelog for a full list of changes. 8.0.2 This release fixes multiple issues with Ren'Py 8.0.1. The changelog for a full list of changes. Have pauses that will expire when a modal screen is display. Games can be added to the google play store. Release History and Updates 8.0.3 This release updates the Android port to target Android 13, ensuing that These packages are available for direct download at the bottom of this page. When necessary, the Ren'Py SDK will automatically download additional packages, such as text editors and Android/iOS support. It may be modified and distributed under the terms of its license.Īdditional Downloads. Ren'Py is free to download and use for commercial and non-commercial purposes. Each contains the full Ren'Py software development kit, with everything needed to develop Ren'Py games for the Windows, Mac, and Linux platforms the Ren'Py tutorial and "The Question", an example game. An incomplete uninstallation of a program may cause problems, which is why thorough removal of programs is recommended.You only need to download one of these files. There could be other causes why users may not be able to uninstall Editra.
Their love for what's scary goes so far as them flirting with any nightmarish monster they come across, such as a bogeyman hiding under their bed or when they desperately wanted Krampus to kidnap them, to the demon's annoyance. Iscream loves all that's gruesome and dark, to the point where they listen to the sound of screams to be able to sleep. In general, Iscream loves to get into all sorts of mischief, even if they'll sometimes believe they are being much more evil than they actually are, thinking that his minor pranks (such as not keeping an elevator door open for others or putting ear flicks on books) are outright atrocities. They enjoy using their demonic powers and shapeshifting to prank and terrorize others, especially the innocent Cheezborger, whom they scared twice by shifting into an horrific biblically accurate angel. They sleep in a bedroom covered in pink flowers which, however, hosts many shadows and monsters and many other examples. Iscream seems to be a oxymoron combination of cute and utterly terrifying: they look like an adorable little bunny, yet are a sadistic, nightmarish demon, with their hobbies ranging from putting on comfy sweaters to harvesting blood so as to perform demonic rituals (which, in turn, they sometimes do just so the summoned demon can scratch their head or look at their drawings, which they draw using blood). In one occasion in particular, when they and Fwench Fwy were having a quarrel, Iscream took on the form of a giant, monstrous version of themselves. Although they hide it in their cuter form, Iscream has razor-sharp teeth and often has a jagged mouth when starting to show their true colors.īased on how angry or devious they get or if they want to scare someone, Iscream will reveal more and more of their true, demonic form, their voice getting scarily deep as opposed to its usual cutesy high pitch. When displaying emotion, however, their sclera becomes completely black and their irises become small and red. When fully in their "cute mode", their eyes have a white sclera with very large, pie-eyed pupils with three small red slits in them. While Fwench Fwy has stated that Iscream has a different real form, possibly more nightmarish than any of those they have taken on-screen, the demon almost always dons the appearance of a small rabbit with white fur, while their tongue and the inside of their ears is crimson. 91: The Cars: Candy-O (design by Alberto Vargas)Īlberto Vargas was already the most famous pin-up artist before designing the famous cover for The Cars classic 1979 album Candy-O, but this painting of a stylish redhead, on a car of course, became his most famous piece. The graphic photo of Bushwick Bill at the hospital was as unflinching as their music. Walking a razor-thin line between exploitation and cultural commentary was the Geto Boys’ modus operandi, and nothing exemplified this dynamic more than their famous 1991 album cover art. Listen here: 92: Geto Boys: We Can’t Be Stopped (design by Cliff Blodget) The fact that it looked remarkably low budget only made it funkier. George Clinton’s gonzoid take on outer-space adventure found its perfect match in the effortlessly cool spaceship-party cover for Parliament’s Mothership Connection. Listen here: 93: Parliament: Mothership Connection (photo by David Alexander, design by Gribbitth) Inspired by the album’s themes of the subconscious, the dark sleeve of Billie Eilish’s When We All Fall Asleep, Where Do We Go? served notice that Eilish was here to mess with your head. 94: Billie Eilish: When We All Fall Asleep, Where Do We Go? (design by Kenneth Cappello)Īny artist who dares to look this terrifying on the cover of their first album deserves all the platinum success they get. Since people were already using LPs to store and clean marijuana, the Airplane gave you a cardboard box holder for it, along with the pot, or at least a realistic-looking photo. Jefferson Airplane’s Long John Silver hails from the golden age of elaborate album covers. 95: Jefferson Airplane: Long John Silver (design by Pacific Eye & Ear) On an album that made a mad dash through the whole of pop history, Nick Lowe pictured himself in a bunch of different guises, from rockabilly hoodlum to sensitive balladeer (there were different pics on the US and UK versions), all with tongue firmly in cheek. As he rapped on Wu-Tang’s “Dog Sh_t,”: “Got meals but still grill that old good welfare cheese.” 96: Nick Lowe: Jesus of Cool/Pure Pop for Now People (design by Barney Bubbles) Forgoing any blinged-out tropes, the former Wu-Tang member put a doctored version of his welfare ID card on the front cover of his solo debut, as both a reminder of where he came from and to destigmatize being on public assistance. Whenever hip-hop started to take itself too seriously, ODB was there to disrupt, agitate, and give the middle finger to convention. Listen here: 97: Ol’ Dirty Bastard: Return to the 36 Chambers: The Dirty Version (design by Alli Truch, photo by Danny Clinch) Put the notorious bathroom cover together with the engraved invitation on the US replacement, and you’ve got the yin and the yang of The Rolling Stones at the time. Listen here: 98: The Rolling Stones: Beggars Banquet (design by Barry Feinstein)īeggars Banquet is a rare case where an album’s two famous covers really complement each other. The red velvet cover, with gold embossed lettering, served notice that Odessa was going to be unique and beautiful, which it was. If The Beatles could do a double “ White Album,” the Bee Gees could do a fuzzy red one. On their 1969 debut, the cavorting characters were there to remind you how much fun rock’n’roll was supposed to be. Bandleader Cyril Jordan’s terrific comic art has turned up on numerous The Flamin’ Groovies covers and posters over the decades. Typosquatting, a form of cybersquatting, is based on Internet users mistyping the name of a popular Web site. The Denver Guardian was a blog site registered in 2016 that claimed to be a legitimate newspaper in Denver, but only ran a single fabricated story that went viral. The site published only fake stories, usually with a realistic clickbait headline, albeit with story-details containing enough flaws that the "discerning reader would likely notice" it was false. Ī was a fake news website that "crudely" spoofed legitimate journalistic organization ABC News, but was in reality completely unrelated. Exact copies can trick viewers into believing the website is an official organization such as the Bloomberg.ma or. This can come in two forms, either by copying a popular news organization's website formatting and pretending to be a lesser known publication or by completely copying an existing website down to its name and authors. Impersonation Īnother method of gaining readers is impersonating a legitimate news organization. Because it is difficult to determine what content exactly is fake news, the website uses a data set to calculate the likelihood of a headline being clickbait. įacebook's Vice President of News Feed says the social media giant defines clickbait "as headlines that withhold significant amounts of information and mislead the user". Additionally, out-of-context or manipulated images can cause readers to incorrectly assume an article's legitimacy, often due to their inflammatory image choice. This became especially relevant in the 2016 election. When linked to from other sites, usually social media, having an extraordinary story title played a large part in tricking users who cannot tell if the article is real or not. This method of enticing readers to view content on their website often leads to exaggerated or even fake titles. Methods įake news websites use a variety of methods to fool their readers into believing their content, either by attempting to persuade the readers that they are legitimate or by distracting readers with incredible news.įictional examples of clickbait chumbox advertsįake news websites often have article titles that are incredible, prompting the user to click on it and read more. Subsequent to that election, the issue of fake news turned into a political weapon between supporters of Clinton and Trump due to these back-and-forth complaints, the definition of fake news as used for such argumentation became vaguer. However, prior to the election between Hillary Clinton and Donald Trump, fake news had not impacted the election process to such a high degree. The New York Times noted in a December 2016 article that fake news had previously maintained a presence on the Internet and within tabloid journalism in years prior to the 2016 U.S. is a high-value ad consumer and extraordinary claims are more likely to be believed during a political crisis. Many sites directly targeted the United States both because the U.S. Many sites originate in or are promoted by Russia, North Macedonia, Romania, and the United States. These sites are distinguished from news satire as fake news articles are usually fabricated to deliberately mislead readers, either for profit or more ambiguous reasons, such as disinformation campaigns. 5 Spread and identification of fake newsįake news websites deliberately publish hoaxes, propaganda, and disinformation to drive web traffic inflamed by social media. 4 Notable examples of fake news websites. "China's COSCO Container Lines is studying the possibility of resuming operation at Iranian ports. “While NITC continues to be the market leader in terms of the number of ships deployed for loading crude from Iran, other companies with ships loading from the country include Dynacom, Delta Tankers, Euronav, Polembros, COSCO, Avin International, Olympic Shipping and Management, New Shipping and Thenamaris, it said.” ( Platts, " Tankers: Sharp Rise in Iran's Crude Oil Shipments to Europe," March 2017). 'deeply concerned' about untrackable China ships carrying Iran oil: officials," ).Īccording to publicly available shipping information, LPG Tankers SEA DOLPHIN (IMO: 9195494) and SEA GLORIA (IMO: 9005053), technically managed by COSCO Shipping Seaman, have called at an Iranian port on two occasions, most recently in January 2019.Īs of August 27, 2019, COSCO is listed on the Illinois Investment Policy Board list of Iran restricted companies.Īccording to publicly accessible ship-monitoring data, since January 1, 2016, vessels for which COSCO Shanghai is the Operator have called at Iranian ports. According to publicly accessible ship-monitoring data, since January 1, 2016, vessels for which COSCO Shipping Specialized is the Operator have called at Iranian ports. 7, ship tracking data on Refinitiv Eikon showed." (Reuters, " U.S. Days later, 14 COSCO Shipping Tanker (Dalian) vessels, about one-third of its fleet, stopped sending location data from their automatic identification system (AIS) between Sept. imposed sanctions on five Chinese individuals and two Chinese COSCO Shipping Corp subsidiaries, saying they had shipped Iranian crude oil in violation of the sanctions. According to the PCC website, PCC offers tracking of COSCO containers (PCC, “ Tracking”). pressure on Iran to continue despite lifting sanctions on China's COSCO unit, official says," ).ĬOSCO’ has apparent business ties to the sanctioned Iranian entity, Petrochemical Commercial Company (“PCC”). "The Treasury said it deleted COSCO Shipping Tanker (Dalian) Co from its sanctions list but continues to blacklist a second unit - COSCO Shipping Tanker (Dalian) Seaman & Ship Management Co Ltd." (Reuters, " U.S. CalSTRS subsequently removed the “Divested and Restricted” status." In 2020, OFAC lifted the sanctions on the COSCO Shipping Energy Transportation. In 2019, CalSTRS designated COSCO Shipping Energy Transportation as “Divested and Restricted” after OFAC added one of its subsidiaries to the list of Specially Designated Nationals. is a wholly-owned subsidiary of COSCO Shipping Energy Transportation. to the list of Specially Designated Nationals (“SDN”) relating to Iran. "On September 25, 2019, OFAC added COSCO Shipping Tanker (DALIAN) Co., Ltd. CalPERS has commenced the review process to determine whether the company meets the threshold criteria for consideration under the Act." "A subsidiary of the company has been identified as potentially providing shipping services for Iranian oil. CalPERS continues to monitor the company for possible changes in status relevant to the Act." In 2020 CalPERS changed the designation to “being monitored” because CalPERS’ initial screening has not identified the company as having involvement in the regions and/or activities targeted by the Act. In 2019 CalPERS designated the company as under review. While this vast county was being carved into many smaller ones, early in the 19th century, many people continued to call the region Old Bourbon. One of these original, huge counties was Bourbon, established in 1785 and named after the French royal family. When American pioneers pushed west of the Allegheny Mountains following the American Revolution, the first counties they founded covered vast regions. It included the current Bourbon County in Kentucky, which became a county when Kentucky separated from Virginia as a new state in 1792. This region included much of today's Eastern Kentucky, including 34 of the modern counties. Īnother proposed origin of the name is the association with the geographic area known as Old Bourbon, consisting of the original Bourbon County in Virginia organized in 1785. He proposes the whiskey was named after Bourbon Street in New Orleans, a major port where shipments of Kentucky whiskey sold well as a cheaper alternative to French cognac. The late date of the Bourbon County etymology has led historian Michael Veach to dispute its authenticity. Essentially, any type of grain can be used to make whiskey, and the practice of aging whiskey and charring the barrels for better flavor had been known in Europe for centuries. There likely was no single "inventor" of bourbon, which developed into its present form in the late 19th century. Similarly, the Spears story is a local favorite but is rarely repeated outside the county. Īlthough still popular and often repeated, the Craig legend is apocryphal. In Bourbon County, across the county line from Craig's distillery in what was then Fayette County, an early distiller named Jacob Spears is credited with being the first to label his product as Bourbon whiskey. The origin of bourbon as a distinct form of whiskey is not well documented and there are many conflicting legends and claims.įor example, the invention of bourbon is often attributed to Elijah Craig, a Baptist minister and distiller credited with many Kentucky firsts (e.g., fulling mill, paper mill, ropewalk) who is said to have been the first to age the product in charred oak casks, a process that gives bourbon its brownish color and distinctive taste. ĭistilling was most likely brought to present-day Kentucky in the late 18th century by Scots, Scots-Irish, and other settlers (including English, Irish, Welsh, German, and French) who began to farm the area in earnest. from at least 51% corn and stored in a new container of charred oak. Bourbon sold in the United States must be produced in the U.S. īourbon was recognized in 1964 by the United States Congress as a "distinctive product of the United States". distillers derived $3.6 billion in revenue from bourbon and Tennessee whiskey (a closely related spirit produced in the state of Tennessee). According to the Distilled Spirits Council of the United States, in 2018 U.S. As of 2014, distillers' wholesale market revenue for bourbon sold within the US was about $2.7 billion, and bourbon made up about two thirds of the $1.6 billion of U.S. Although bourbon may be made anywhere in the United States, it is strongly associated with the American South in general, and with Kentucky in particular. īourbon has been distilled since the 18th century. The name "Bourbon" was not applied until the 1850s, and the Kentucky etymology was not advanced until the 1870s. The name derives from the French Bourbon dynasty, although the precise inspiration is uncertain contenders include Bourbon County in Kentucky and Bourbon Street in New Orleans, both of which are named after the dynasty. Generally associated with the American SouthĬorn whiskey, Straight whiskey, Tennessee whiskeyīourbon ( / b ɜːr b ən/) is a type of American whiskey, a barrel-aged distilled liquor made primarily from corn. A selection of bourbons and Tennessee whiskeys at a liquor store. Nutrition Calories Grilled Chicken Wrap Calories 765 Fat 2.9g Carbohydrates 25g Protein 13g Saturated Fat 0.9g Fiber 1.5g Salt 0.79g Sugar 2.9g Important Note: The nutritional information is based on standard product formulations and serving sizes. To keep your diet plan on track, it’s important to calculate McDonald’s Calories and Nutrition Facts before you order.Īccording to the McDonald’s website, the Spicy Grilled Chicken Wrap Calories table is prepared. If McDonald’s Grilled Chicken Wrap sounds delicious to you, you might be wondering about its nutritional values.Ĭan you make the Grilled Chicken Wrap a staple for starters’ order? Let’s examine the Calories and find out Nutritional Value! McDonald’s Grilled Chicken Wrap Calories That’s why, here, I am providing details about the yummy Grilled Chicken Wrap based on the calories. Here you can easily find McDonald’s Grilled Chicken Wrap Calories, fat, protein, Carbs, Ingredients, and other nutrition information.īefore you enter into McDonald’s App or Restaurant, you need to decide which food is to be kept away, and how to try different combinations of items in McDonald’s Menu, to keep your calorie count low. It has also added healthier ‘Sides’ you can choose organic milk or water with their Happy Meals and swap out Fries for Carrot Sticks or Fruit Bags. However, we use flour all day to bread our chicken and there could be gluten/flour cross contact, so we can not guarantee 100% gluten free.Calories in McDonald’s Grilled Chicken Wrap: McDonald’s is known to have some pretty crazy fast food menu, it has added a healthy grilled chicken wrap to its children’s Happy Meal Menu. Our Fries, Coleslaw, and Potato Salad are gluten free. We fry our fries in beef fat, but truth be told, a lot of vegetarians eat our fries.ĭO YOU HAVE ANY GLUTEN FREE OPTIONS? - Unfortunately, not really. Please note, we do not carry lettuce nor tomato.ĭO YOU HAVE ANY VEGETARIAN OPTIONS? - Yes, we have a secret menu item called the Veggie Sandwich and it is amazing! It has fries, coleslaw, cheese, pickles, mild rub, and coop sauce on a toasted brioche bun.ĪRE THE FRIES 100% VEGETARIAN? - No, our fries are not 100% vegetarian. However, we keep things pretty simple and we recommend you try everything as is. It brings a little sweetness and crunch to our waffles.ĬAN I ADD “X,Y,Z” TO MY ORDER? - Yes, you can customize your order. It comes in little course balls and it is used in our waffles. HOW BIG IS YOUR ORDER OF FRIES? - Our fries are 5.5 ounces, which is equivalent to a larger fry.ĭO YOU DO CATERING? - Yes we do! Please email: IS PEARL SUGAR? - Pearl sugar is refined compressed white sugar. Plus, frying in beef fat just tastes better! We strongly believe in delivering the best product possible and this is a huge part of that. People have been cooking with animal fat since the beginning of time and it is a more natural way of cooking. Beef tallow on the other hand is a saturated fat and contains a number of benefits including an excellent source of Vitamin A, D and E and Fatty Acids that you wont get from a trans fat oil. Trans fat cooking oils (vegetable oil, canola oil, peanut oil, etc) are very bad for you and after heated to 350 degrees, it create a chemical call Aldehyde. WHY DO YOU USE BEEF FAT FOR FRYING? - Beef fat is a saturated fat vs. We have looked everywhere! When it is accessible, we will make it happen, but that may not be for 2-5 years. Currently, Halal certified beef fat does not exist in large quantities for restaurants. Unfortunately, that beef fat is not Halal. However, we fry all our chicken and fries in beef fat. IS YOUR CHICKEN HALAL? - Yes, our chicken is 100% Halal certified. HOW HOT IS HOT? - Our Hot is ridiculously spicy! It is no joke! Ghost pepper is the main spice in our “Hot” heat level and we estimate it is 1,000,000 on the scoville scale. They can save files and URLs in the document and make the website much better with standardized coding. Right from using colors for value types to inspecting all the elements, the Free JSON Editor is an ideal choice for web developers. Edit, add, move, remove, and duplicate fields and values. The undo and redo options make it very manageable as users can make any changes without having to worry about the errors. Visual JSON Editor (Windows) is a JSON schema based file editor: When opening a JSON file, the application auto-generates an editor GUI based on the provided JSON schema. Users can search and replace text in the tree view and change the value types as well. If there are any duplicate fields, the same can be identified within no time and removed from the JSON. Because of the view, users can get the editing done with ease as they can simultaneously parse the document. The Free JSON Editor has an interface which can be comprehended by even those who are using the software for the first time. It does not eat up much of the disk space either as it is a small sized tool. Therefore, there is no harm done to the speed and performance of the device. The tool is safe as it does not contain any virus. There are a number of functions such as syntax highlighting, text highlighting using colors, validation, and all these can be accomplished with just a few clicks. Once it is installed onto a device, it can be used for as long as there is a requirement. The software is available to be downloaded for free and there are no trial versions of the same. It displays the content in an outline tree view and lets web developers edit, parse and save the changes in very simple steps. The Free JSON Editor is a tool that allows users to open, edit and format JSON, which is a data format used in designing websites. |
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